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In 1818 a Sunday school in Broad Chalke was attended by 70 children. By 1846 both a day school and a Sunday school had been established, attended by 200 pupils, with 48 only attending on a Sunday. A mistress was paid £37.12.0 and the expenses of the school, approximately £70 a year, were met by the curate, voluntary subscriptions and the payment of fees. The first school log book entry is for 1863, and this states that a new schoolroom was built in 1860. An inspector's report in 1858 shows that the children were being taught in a temporary building and that a site had been promised for a new school.
In 1863 the staff consisted of a master, a pupil teacher and a sewing mistress who was the master's wife. The master was also expected to run the night school, which was open for five months of the year from October to February. His salary for each job was £20 and £5 respectively. Alongside the grant given to the school, each child had to pay a fee. Farmers' and tradesmen's children paid 3d a week, artisan's children 2d and labourer's children 1d. By 1875 the staffing had increased to four, when the headmaster was assisted by pupil teachers and monitors.
The school was divided into two rooms. The main room, in which the older children were taught by the master, was 54 feet long and 15 feet wide. The smaller classroom, where the younger children were taught by the pupil teacher, was 27 feet long and 12 feet wide.